Magnetic metal-organic frameworks

被引：2306
|
作者：
Kurmoo, Mohamedally [1 ]
机构：
[1] Univ Strasbourg, Chim Coordinat Organ Lab, CNRS, UMR7140, F-67000 Strasbourg, France
来源：
CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 05期
基金：
英国工程与自然科学研究理事会;
关键词：
SINGLE-CHAIN MAGNETS; COBALT(II) COORDINATION POLYMERS; ORBITAL ANGULAR-MOMENTUM; SECONDARY BUILDING UNITS; HYDROTHERMAL SYNTHESIS; CRYSTAL-STRUCTURE; DIAMOND FRAMEWORK; WEAK FERROMAGNETISM; LONG-RANGE; SOLVOTHERMAL SYNTHESIS;
D O I：
10.1039/b804757j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The purpose of this critical review is to give a representative and comprehensive overview of the arising developments in the. field of magnetic metal-organic frameworks, in particular those containing cobalt(II). We examine the diversity of magnetic exchange interactions between nearest-neighbour moment carriers, covering from dimers to oligomers and discuss their implications in infinite chains, layers and networks, having a variety of topologies. We progress to the different forms of short-range magnetic ordering, giving rise to single-molecule-magnets and single-chain-magnets, to long-range ordering of two- and three-dimensional networks (323 references).
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页码：1353 / 1379
页数：27
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