Synthesis of β-hydroxysulfides from alkenes under supramolecular catalysis in the presence of β-cyclodextrin in water

被引：78
|
作者：
Surendra, K. [1 ]
Krishnaveni, N. Srilakshmi [1 ]
Sridhar, R. [1 ]
Rao, K. Rama [1 ]
机构：
[1] Indian Inst Chem Technol, Div Organ Chem 1, Hyderabad 500007, Andhra Pradesh, India
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 15期
关键词：
D O I：
10.1021/jo060805a
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An environmentally benign and highly efficient procedure has been developed for the direct one-pot synthesis of beta-hydroxysulfides in good yields under neutral conditions from alkenes and thiophenols in the presence of aerial oxygen using beta-cyclodextrin in water. This protocol tolerates a wide variety of functional groups or substrates and does not require the use of either acid or base catalysts. beta-Cyclodextrin can be recovered and reused for a number of runs without any loss of activity.
引用
收藏
页码：5819 / 5821
页数：3
相关论文
共 50 条
  • [1] Synthesis of thiazoles and aminothiazoles from β-keto tosylates under supramolecular catalysis in the presence of β-cyclodextrin in water
    Kumar, V. Pavan
    Narender, M.
    Sridhar, R.
    Nageswar, Y. V. A.
    Rao, K. Rama
    [J]. SYNTHETIC COMMUNICATIONS, 2007, 37 (22-24) : 4331 - 4336
  • [2] Synthesis of β-hydroxy selenides using benzeneselenol and oxiranes under supramolecular catalysis in the presence of β-cyclodextrin in water
    Sridhar, R
    Srinivas, B
    Surendra, K
    Krishnaveni, NS
    Rao, KR
    [J]. TETRAHEDRON LETTERS, 2005, 46 (51) : 8837 - 8839
  • [3] Supramolecular catalysis of strecker reaction in water under neutral conditions in the presence of β-cyclodextrin
    Surendra, K
    Krishnaveni, NS
    Mahesh, A
    Rao, KR
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (06): : 2532 - 2534
  • [4] Supramolecular catalysis by β-cyclodextrin for the synthesis of kojic acid derivatives in water
    Kataev, Evgeny A.
    Reddy, Mittapalli Ramana
    Reddy, Gangarpu Niranjan
    Reddy, Vemulapati Hanuman
    Reddy, Cirandur Suresh
    Reddy, Basi V. Subba
    [J]. NEW JOURNAL OF CHEMISTRY, 2016, 40 (02) : 1693 - 1697
  • [5] Supramolecular synthesis of selenazoles using selenourea in water in the presence of β-cyclodextrin under atmospheric pressure
    Narender, M.
    Reddy, M. Somi
    Kumar, V. Pavan
    Reddy, V. Prakash
    Nageswar, Y. V. D.
    Rao, K. Rama
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (05): : 1849 - 1851
  • [6] β-Cyclodextrin promoted allylation of aldehydes with allyltributyltin under supramolecular catalysis in water
    Krishnaveni, NS
    Surendra, K
    Kumar, VP
    Srinivas, B
    Reddy, CS
    Rao, KR
    [J]. TETRAHEDRON LETTERS, 2005, 46 (25) : 4299 - 4301
  • [7] Novel and efficient supramolecular synthesis of pyrroles in the presence of β-cyclodextrin in water
    Ramesh, K.
    Karnakar, K.
    Satish, G.
    Nageswar, Y. V. D.
    [J]. CHINESE CHEMICAL LETTERS, 2012, 23 (12) : 1331 - 1334
  • [8] Novel and efficient supramolecular synthesis of pyrroles in the presence of β-cyclodextrin in water
    K.Ramesh
    K.Karnakar
    G.Satish
    Y.V.D.Nageswar
    [J]. Chinese Chemical Letters, 2012, 23 (12) : 1331 - 1334
  • [9] Highly regioselective thiolysis of oxiranes under supramolecular catalysis involving β-cyclodextrin in water
    Reddy, M. Somi
    Srinivas, B.
    Sridhar, R.
    Narender, M.
    Rao, K. Rama
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2006, 255 (1-2) : 180 - 183
  • [10] Multicomponent Approach Towards the Synthesis of Substituted Pyrroles under Supramolecular Catalysis Using β-Cyclodextrin as a Catalyst in Water Under Neutral Conditions
    Murthy, Sabbavarapu Narayana
    Madhav, Bandaru
    Kumar, Akkiligunta Vijay
    Rao, Kakulapati Rama
    Nageswar, Yadavalli Venkata Durga
    [J]. HELVETICA CHIMICA ACTA, 2009, 92 (10) : 2118 - 2124
12345