Supramolecular catalysis of strecker reaction in water under neutral conditions in the presence of β-cyclodextrin

被引：106
|
作者：
Surendra, K [1 ]
Krishnaveni, NS [1 ]
Mahesh, A [1 ]
Rao, KR [1 ]
机构：
[1] Indian Inst Chem Technol, Organ Chem Div 1, Hyderabad 500007, Andhra Pradesh, India
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2006年 / 71卷 / 06期
关键词：
D O I：
10.1021/jo052510n
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] An environmentally benign and highly efficient procedure for the nucleophilic addition of trimethylsilyl cyanide to imines (Strecker reaction) has been developed under biomimetic conditions in water in the presence of beta-cyclodextrin to afford alpha-aminonitriles in quantitative yields. The use of cyclodextrin precludes the use of either acid or base, and the catalyst can be recycled a number of times without loss in activity.
引用
收藏
页码：2532 / 2534
页数：3
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