Nucleophilic addition of alcohols to anionic [2-B10H9NCR]- (R = Et, t-Bu): An approach to producing new borylated imidates

被引：24

作者：

Zhdanov, A. P. ^{[1
]}

Klyukin, I. N. ^{[1
]}

Bykov, A. Yu. ^{[1
]}

Grigoriev, M. S. ^{[2
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Leninskii Pr 31, Moscow 119991, Russia

[2] Russian Acad Sci, Frumkin Inst Phys Chem & Electrochem, Obrucheva St 40, Moscow 117342, Russia

来源：

POLYHEDRON | 2017年 / 123卷

关键词：

Closo-borate anion; Boron cluster; Nitrilium derivatives; Borylated imidates; Nucleophilic addition; CLOSO-DECABORATE ANION; NITRILIUM DERIVATIVES; OXYGEN BONDS; CLUSTERS; SUBSTITUENTS; CYCLOADDITION; REACTIVITY; CLEAVAGE; ACIDS;

D O I：

10.1016/j.poly.2016.11.035

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The interaction between nitrilium derivatives of the closo-decaborate cluster [2-B10H9NCR](-) (R = Et, t-Bu) with a number of aliphatic alcohols has been considered. The dependence between the type and composition of the final products and the structure of nitrilium derivatives and corresponding alcohols was studied. Compounds obtained were characterized by IR and NMR (H-1, B-11, C-13) spectroscopy. The crystal structures of some derivatives of the closo-decaborate anion were determined by X-ray diffraction. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：176 / 183

页数：8

共 8 条

[1] Synthesis of New Boron-Containing Ligands Based on the Nucleophilic Addition of 1,10-Phenanthroline-5-Amine to Nitrile Derivatives of [2-B10H9NCR]- (R = Me, Et, nPr)
Nelyubin, A. V.
Selivanov, N. A.
Bykov, A. Yu.
Kubasov, A. S.
Klyukin, I. N.
Zhdanov, A. P.
Zhizhin, K. Yu.
Kuznetsov, N. T.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2024, 69 (06) : 818 - 823
[2] Nucleophilic Addition of Aliphatic Diamines NH2(CH2)nNH2 (n = 6, 9) to Nitrilium Derivatives of the closo-Decaborate Anion [2-B10H9NCR]– (R = CH3, C2H5, nC3H7)
V. V. Voinova
N. A. Selivanov
A. Yu. Bykov
I. N. Klyukin
A. P. Zhdanov
K. Yu. Zhizhin
N. T. Kuznetsov
Russian Journal of Inorganic Chemistry, 2023, 68 : 1343 - 1348
[3] Nucleophilic Addition of Aliphatic Diamines NH2(CH2)nNH2 (n=6, 9) to Nitrilium Derivatives of the closo-Decaborate Anion [2-B10H9NCR]- (R = CH3, C2H5, nC3H7)
Voinova, V. V.
Selivanov, N. A.
Bykov, A. Yu.
Klyukin, I. N.
Zhdanov, A. P.
Zhizhin, K. Yu.
Kuznetsov, N. T.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 68 (10) : 1343 - 1348
[4] Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(N≡CMe)]−
A. P. Zhdanov
M. V. Lisovsky
L. V. Goeva
G. A. Razgonyaeva
I. N. Polyakova
K. Yu. Zhizhin
N. T. Kuznetsov
Russian Chemical Bulletin, 2009, 58 : 1694 - 1700
[5] Nucleophilic addition of alcohols to the C-N multiple bonds of the nitrilium substituent in the anion [2-B10H9(Naparts per thousandCMe)]-
Zhdanov, A. P.
Lisovsky, M. V.
Goeva, L. V.
Razgonyaeva, G. A.
Polyakova, I. N.
Zhizhin, K. Yu.
Kuznetsov, N. T.
RUSSIAN CHEMICAL BULLETIN, 2009, 58 (08) : 1694 - 1700
[6] Synthesis of New Iminium Derivatives of Sulphonio-сloso-Decaborate Anion (Bu4N)[2-B10H9SC(NH2)R] (R = -CH3, -CH2CH3, -CH(CH3)2, -Ph, -PhCH3)
Golubev, A. V.
Kubasov, A. S.
Lukoshkova, A. A.
Sarkisov, N. A.
Novikov, I. V.
Starodubets, P. A.
Bykov, A. Yu.
Zhdanov, A. P.
Zhizhin, K. Yu.
Kuznetsov, N. T.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 68 (12) : 1752 - 1760
[7] Synthesis of New Iminium Derivatives of Sulphonio-сloso-Decaborate Anion (Bu4N)[2-B10H9SC(NH2)R] (R = –CH3, –CH2CH3, –CH(CH3)2, –Ph, –PhCH3)
A. V. Golubev
A. S. Kubasov
A. A. Lukoshkova
N. A. Sarkisov
I. V. Novikov
P. A. Starodubets
A. Yu. Bykov
A. P. Zhdanov
K. Yu. Zhizhin
N. T. Kuznetsov
Russian Journal of Inorganic Chemistry, 2023, 68 : 1752 - 1760
[8] New nickel-antimony carbonyl clusters: Stereochemical analyses of the [Ni-10(SbR)(2)(CO)(18)](2-) dianions (R=Me, Et, Pr-i, Bu-t, p-FC6H4) containing empty 1,12-Ni10Sb2 icosahedral cages and of the unprecedented stibinido-bridged 34-electron Ni-2(CO)(4)(mu(2)-Sb Bu-t(2))(2) dimer
Mlynek, PD
Dahl, LF
ORGANOMETALLICS, 1997, 16 (08) : 1641 - 1654

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