Synthesis of New Boron-Containing Ligands Based on the Nucleophilic Addition of 1,10-Phenanthroline-5-Amine to Nitrile Derivatives of [2-B10H9NCR]- (R = Me, Et, nPr)

被引：0

作者：

Nelyubin, A. V. ^{[1
]}

Selivanov, N. A. ^{[1
]}

Bykov, A. Yu. ^{[1
]}

Kubasov, A. S. ^{[1
]}

Klyukin, I. N. ^{[1
]}

Zhdanov, A. P. ^{[1
]}

Zhizhin, K. Yu. ^{[1
]}

Kuznetsov, N. T. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2024年 / 69卷 / 06期

基金：

俄罗斯科学基金会;

关键词：

closo-decaborate anion; borylated amidines; substituted phenanthrolines; CLOSO-DECABORATE ANION; BORATE COMPLEXES; METHANE; AMINES; COBALT;

D O I：

10.1134/S0036023624600758

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of substituted derivatives of the closo-decaborate anion of 1,10-phenanthroline-5-amine have been prepared in this work. The products have been identified by multinuclear NMR spectroscopy, ESI-mass spectrometry, and IR spectroscopy. The structure of compound (NBu4)[2-B10H9NHC(C2H5)HNC12H7N2] was established by single crystal X-ray diffraction.

引用

页码：818 / 823

页数：6

共 3 条

[1] Nucleophilic addition of alcohols to anionic [2-B10H9NCR]- (R = Et, t-Bu): An approach to producing new borylated imidates
Zhdanov, A. P.
Klyukin, I. N.
Bykov, A. Yu.
Grigoriev, M. S.
Zhizhin, K. Yu.
Kuznetsov, N. T.
POLYHEDRON, 2017, 123 : 176 - 183
[2] Nucleophilic Addition of Aliphatic Diamines NH2(CH2)nNH2 (n = 6, 9) to Nitrilium Derivatives of the closo-Decaborate Anion [2-B10H9NCR]– (R = CH3, C2H5, nC3H7)
V. V. Voinova
N. A. Selivanov
A. Yu. Bykov
I. N. Klyukin
A. P. Zhdanov
K. Yu. Zhizhin
N. T. Kuznetsov
Russian Journal of Inorganic Chemistry, 2023, 68 : 1343 - 1348
[3] Nucleophilic Addition of Aliphatic Diamines NH2(CH2)nNH2 (n=6, 9) to Nitrilium Derivatives of the closo-Decaborate Anion [2-B10H9NCR]- (R = CH3, C2H5, nC3H7)
Voinova, V. V.
Selivanov, N. A.
Bykov, A. Yu.
Klyukin, I. N.
Zhdanov, A. P.
Zhizhin, K. Yu.
Kuznetsov, N. T.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2023, 68 (10) : 1343 - 1348

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