Copper(II) complexes of formylpyrazine N(4)-substituted thiosemicarbazones

被引:19
|
作者
West, DX
Lockwood, MA
Owens, MD
Liberta, AE
机构
[1] Department of Chemistry, Illinois State University, Normal
关键词
D O I
10.1023/A:1018513919016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Copper(II) complexes of formylpyrazine N(4)-substituted thiosemicarbazones coordinated either as neutral or monoanionic ligands, [M(HL)X-2] and [M(L)X], respectively, have been prepared and characterized. I.r., electronic and e.s.r spectra of the complexes, as well as H-1-n.m.r. spectra of the thiosemicarbazones, have been obtained. The N(4)-dialkyl and azacyclothiosemicarbazones and their copper(II) complexes show significant growth inhibitory activity against both Aspergillus niger and Paecilomyces variotii.
引用
收藏
页码:366 / 371
页数:6
相关论文
共 50 条
  • [31] Nickel(II) and copper(II) complexes of 5-substituted-salicylaldehyde thiosemicarbazones
    Douglas X. West
    Michelle M. Salberg
    Gordon A. Bain
    Anthony E. Liberta
    [J]. Transition Metal Chemistry, 1997, 22 : 180 - 184
  • [32] Cobalt(II) and nickel(II) complexes of N(4′) substituted 3- and 4-acetylpyridine thiosemicarbazones
    Heloisa Beraldo
    Wanderlene F. Nacif
    Leticia R. Teixeira
    Julio S. Rebouças
    [J]. Transition Metal Chemistry, 2002, 27 : 85 - 88
  • [33] Copper(II) and nickel(II) complexes of 2,3-butanedione bis(N(3)-substituted thiosemicarbazones)
    West, DX
    Ives, JS
    Bain, GA
    Liberta, AE
    ValdesMartinez, J
    Ebert, KH
    HernandezOrtega, S
    [J]. POLYHEDRON, 1997, 16 (11) : 1895 - 1905
  • [34] Cobalt(II) and nickel(II) complexes of N(4′) substituted 3-and 4-acetylpyridine thiosemicarbazones
    Beraldo, H
    Nacif, WF
    Teixeira, LR
    Rebouças, JS
    [J]. TRANSITION METAL CHEMISTRY, 2002, 27 (01) : 85 - 88
  • [35] Copper(II) complexes of 2-benzoylpyridine N-4-substituted thiosemicarbazones (vol 14, pg 2189, 1995)
    West, DX
    Ives, JS
    Krejci, J
    Salberg, MM
    Zumbahlen, TL
    Bain, GA
    Liberta, AE
    ValdesMartinez, J
    HernandezOrtega, S
    Toscano, RA
    [J]. POLYHEDRON, 1996, 15 (14) : 2467 - 2467
  • [36] Multiple mechanisms for cytotoxicity induced by copper(II) complexes of 2-acetylpyrazine-N-substituted thiosemicarbazones
    Miller, MC
    Stineman, CN
    Vance, JR
    West, DX
    Hall, IH
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 1999, 13 (01) : 9 - 19
  • [37] THE CYTOTOXICITY OF COPPER(II) COMPLEXES OF HETEROCYCLIC THIOSEMICARBAZONES AND 2-SUBSTITUTED PYRIDINE N-OXIDES
    WEST, DX
    LIBERTA, AE
    RAJENDRAN, KG
    HALL, IH
    [J]. ANTI-CANCER DRUGS, 1993, 4 (02) : 241 - 249
  • [38] DINUCLEAR NICKEL(II) COMPLEXES OF 2-HYDROXYACETOPHENONE N-4-SUBSTITUTED THIOSEMICARBAZONES
    WEST, DX
    YANG, YH
    KLEIN, TL
    GOLDBERG, KI
    LIBERTA, AE
    VALDESMARTINEZ, J
    HERNANDEZORTEGA, S
    [J]. POLYHEDRON, 1995, 14 (20-21) : 3051 - 3060
  • [39] COPPER(II) COMPLEXES OF 4-SUBSTITUTED N,N-DIMETHYLBENZAMIDES
    STEINHAUS, RK
    BROWN, DJ
    [J]. INORGANICA CHIMICA ACTA-LETTERS, 1981, 53 (06): : L253 - L255
  • [40] Copper(II) complexes of N(4)-substituted thiosemicarbazones derived from pyridine-2-carbaldehyde:: Crystal structure of a binuclear complex
    Rapheal, P. F.
    Manoj, E.
    Kurup, M. R. Prathapachandra
    [J]. POLYHEDRON, 2007, 26 (04) : 818 - 828