Copper(II) complexes of formylpyrazine N(4)-substituted thiosemicarbazones

被引:19
|
作者
West, DX
Lockwood, MA
Owens, MD
Liberta, AE
机构
[1] Department of Chemistry, Illinois State University, Normal
关键词
D O I
10.1023/A:1018513919016
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Copper(II) complexes of formylpyrazine N(4)-substituted thiosemicarbazones coordinated either as neutral or monoanionic ligands, [M(HL)X-2] and [M(L)X], respectively, have been prepared and characterized. I.r., electronic and e.s.r spectra of the complexes, as well as H-1-n.m.r. spectra of the thiosemicarbazones, have been obtained. The N(4)-dialkyl and azacyclothiosemicarbazones and their copper(II) complexes show significant growth inhibitory activity against both Aspergillus niger and Paecilomyces variotii.
引用
收藏
页码:366 / 371
页数:6
相关论文
共 50 条
  • [1] Copper(II) complexes of formylpyrazine N(4)-substituted thiosemicarbazones
    Douglas X. West
    Mark A. Lockwood
    Matthew D. Owens
    Anthony E. Liberta
    [J]. Transition Metal Chemistry, 1997, 22 : 366 - 371
  • [2] Copper(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones
    West, DX
    Beraldo, H
    Nassar, AA
    El-Saied, FA
    Ayad, MI
    [J]. TRANSITION METAL CHEMISTRY, 1999, 24 (04) : 421 - 424
  • [3] Copper(II) complexes of 4-acetamidobenzaldehyde N(4)-substituted thiosemicarbazones
    Douglas X. West
    Heloisa Beraldo
    Amal A. Nassar
    Fathy A. El-Saied
    Mohammed I. Ayad
    [J]. Transition Metal Chemistry, 1999, 24 : 421 - 424
  • [4] Copper(II) complexes of 4-formylantipyrine N(4)-substituted thiosemicarbazones
    ElSawaf, AK
    West, DX
    ElSaied, FA
    ElBahnasawy, RM
    [J]. TRANSITION METAL CHEMISTRY, 1997, 22 (04) : 360 - 365
  • [5] Copper(II) complexes of 2-aminoacetophenone N(4)-substituted thiosemicarbazones
    West, DX
    Nassar, AA
    El-Saied, FA
    Ayad, MI
    [J]. TRANSITION METAL CHEMISTRY, 1998, 23 (04) : 321 - 325
  • [6] Copper(II) complexes of 2-aminoacetophenone N(4)-substituted thiosemicarbazones
    Douglas X. West
    Amal A. Nassar
    Fathy A. El-Saied
    Mohamed I. Ayad
    [J]. Transition Metal Chemistry, 1998, 23 : 321 - 325
  • [7] Synthetic and spectroscopic investigations of N(4)-substituted isatin thiosemicarbazones and their copper(II) complexes
    Bain, GA
    West, DX
    Krejci, J
    ValdesMartinez, J
    HernandezOrtega, S
    Toscano, RA
    [J]. POLYHEDRON, 1997, 16 (05) : 855 - 862
  • [8] COPPER(II) COMPLEXES OF 2-BENZOYLPYRIDINE N-4-SUBSTITUTED THIOSEMICARBAZONES
    WEST, DX
    IVES, JS
    KREJCI, J
    SALBERG, MM
    ZUMBAHLEN, TL
    BAIN, GA
    LIBERTA, AE
    VALDESMARTINEZ, J
    HERNANDEZORTIZ, S
    TOSCANO, RA
    [J]. POLYHEDRON, 1995, 14 (15-16) : 2189 - 2200
  • [9] COPPER(II) COMPLEXES OF 6-METHYL-2-ACETYLPYRIDINE N(4)-SUBSTITUTED THIOSEMICARBAZONES
    WEST, DX
    THIENTANAVANICH, I
    LIBERTA, AE
    [J]. TRANSITION METAL CHEMISTRY, 1995, 20 (03) : 303 - 308
  • [10] The cytotoxicity of copper(II) complexes of 2-acetyl-pyridyl-4N-substituted thiosemicarbazones
    Miller, MC
    Stineman, CN
    Vance, JR
    West, DX
    Hall, IH
    [J]. ANTICANCER RESEARCH, 1998, 18 (6A) : 4131 - 4139