Specific Surface Area and Volume Fraction of the Cherry-Pit Model with Packed Pits

被引:17
|
作者
Elsner, A. [1 ]
Wagner, A. [2 ]
Aste, T. [3 ]
Hermann, H. [1 ]
Stoyan, D. [2 ]
机构
[1] IFW Dresden, Inst Solid State & Mat Res, D-01171 Dresden, Germany
[2] TU Bergakad Freiberg, Inst Stochast, D-09596 Freiberg, Germany
[3] Australian Natl Univ, Dept Appl Math, Res Sch Phys Sci & Engn, Canberra, ACT 0200, Australia
来源
JOURNAL OF PHYSICAL CHEMISTRY B | 2009年 / 113卷 / 22期
关键词
CONCENTRIC-SHELL MODEL; RANDOM CLOSE PACKING; LOW-K DIELECTRICS; COMPUTER-SIMULATION; SPHERE PACKINGS; POROSITY; MEDIA; LIQUIDS; PORE;
D O I
10.1021/jp806767m
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper investigates volume fraction phi and specific surface area s for statistically homogeneous systems of partially penetrating spheres, i.e. so-called 'cherry-pit models'. In contrast to the version where the pits form an equilibrium system of hard spheres, here pits or hard spheres are considered which are packed, can be in direct contact, and form a nonequilibrium distribution. For this kind of system, new formulas for phi and s are given, which yield values in good agreement with the ones for large models constructed from hard sphere packings generated both experimentally and numerically. Surprisingly, the existing formulas for phi and s in the equilibrium cherry-pit model lead to values which deviate substantially from the values obtained here.
引用
收藏
页码:7780 / 7784
页数:5
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