Reactions of Mo(NAr)(CH-t-Bu)(CH2-t-Bu)2 with alcohols to give metathesis catalysts of the type Mo(NAr)(CH-t-Bu)(CH2-t-Bu)(OR)

被引：33

作者：

Sinha, A ^{[1
]}

Schrock, RR ^{[1
]}

机构：

[1] MIT, Dept Chem, Cambridge, MA 02139 USA

来源：

ORGANOMETALLICS | 2004年 / 23卷 / 08期

关键词：

D O I：

10.1021/om030639m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction between Mo(NAr)(CH-t-Bu)-(CH2 -t-Bu)(2) and 1 equiv of an alcohol yields either Mo(NAr)(CH-t-Bu)(CH2-t-Bu)(OR) complexes or Mo-(NAr)(CH2-t-Bu)(OR) complexes, which evolve neopentane to yield the former. Preliminary experiments have shown that Mo(NAr)(CH-t-Bu)(CH2-t-Bu)(2)(OR) complexes are active for metathesis conversion of diallyl ether to dihydrofuran and ethylene.

引用

页码：1643 / 1645

页数：3

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