Highly enantioselective transfer hydrogenation of α,β-unsaturated ketones

被引：350

作者：

Martin, Nolwenn J. A. ^{[1
]}

List, Benjamin ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Ruhr, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 41期

关键词：

D O I：

10.1021/ja065708d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe an efficient and highly enantioselective conjugate transfer hydrogenation of α,β-unsaturated ketones that is catalyzed by a salt made from tert-butyl valinate and a recently introduced powerful chiral phosphoric acid catalyst (TRIP). Copyright © 2006 American Chemical Society.

引用

页码：13368 / 13369

页数：2

共 50 条

[21] Probing subtle ligand effects in the enantioselective transfer hydrogenation of ketones
Frost, CG
Mendonça, P
TETRAHEDRON-ASYMMETRY, 2000, 11 (09) : 1845 - 1848
[22] Highly Enantioselective Transfer Hydrogenation of Prochiral Ketones Using Ru(II)-Chitosan Catalyst in Aqueous Media
Szollosi, Gyoergy
Kolcsar, Vanessza Judit
CHEMCATCHEM, 2019, 11 (02) : 820 - 830
[23] Highly enantioselective transfer hydrogenation of aromatic ketones catalyzed by chiral diaminodiphosphine-iridium(I) complexes
Tang, CL
Li, YY
Pan, ED
Zhang, H
Zhou, ZH
Gao, JX
ACTA CHIMICA SINICA, 2001, 59 (10) : 1831 - 1834
[24] Highly Chemo- and Enantioselective Rh-Catalyzed Hydrogenation of β-Sulfonyl-α,β-unsaturated Ketones: Access to Chiral γ-Ketosulfones
Liu, Gang
Yin, Congcong
Yang, Xuanliang
Li, Anqi
Wang, Minyan
Zhang, Xumu
Dong, Xiu-Qin
ORGANIC LETTERS, 2021, 23 (01) : 19 - 24
[25] Chemoselective Transfer Hydrogenation of α,β-Unsaturated Ketones Catalyzed by Iridium Complexes
Xia, Yanping
Ouyang, Lu
Liao, Jianhua
Yang, Xiao
Luo, Renshi
SYNOPEN, 2021, 05 (01): : 36 - 42
[26] Highly enantioselective hydrogenation and transfer hydrogenation of cycloalkyl and heterocyclic ketones catalysed by an iridium complex of a tridentate phosphine-diamine ligand
Fuentes, Jose A.
Carpenter, Ian
Kann, Nina
Clarke, Matthew L.
CHEMICAL COMMUNICATIONS, 2013, 49 (87) : 10245 - 10247
[27] A Hantzsch Amido Dihydropyridine as a Transfer Hydrogenation Reagent for α,β-Unsaturated Ketones
Van Arman, Scott A.
Zimmet, Austin J.
Murray, Ian E.
JOURNAL OF ORGANIC CHEMISTRY, 2016, 81 (09): : 3528 - 3532
[28] Methanol as a hydrogen source: room-temperature highly-selective transfer hydrogenation of α,β-unsaturated ketones
Garg, Nidhi
Somasundharam, Hari Prasaad
Dahiya, Pardeep
Sundararaju, Basker
CHEMICAL COMMUNICATIONS, 2022, 58 (71) : 9930 - 9933
[29] Highly Enantioselective Organocatalytic Sulfa-Michael Addition to α,β-Unsaturated Ketones
Rana, Nirmal K.
Selvakumar, Sermadurai
Singh, Vinod K.
JOURNAL OF ORGANIC CHEMISTRY, 2010, 75 (06): : 2089 - 2091
[30] Development of highly enantioselective oxazaborolidinone catalysts for the reactions of acyclic α,β-unsaturated ketones
Harada, Toshiro
Kusukawa, Takahiro
SYNLETT, 2007, (12) : 1823 - 1835

← 1 2 3 4 5 →