Highly enantioselective transfer hydrogenation of α,β-unsaturated ketones

被引：350

作者：

Martin, Nolwenn J. A. ^{[1
]}

List, Benjamin ^{[1
]}

机构：

[1] Max Planck Inst Kohlenforsch, D-45470 Mulheim, Ruhr, Germany

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 41期

关键词：

D O I：

10.1021/ja065708d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We describe an efficient and highly enantioselective conjugate transfer hydrogenation of α,β-unsaturated ketones that is catalyzed by a salt made from tert-butyl valinate and a recently introduced powerful chiral phosphoric acid catalyst (TRIP). Copyright © 2006 American Chemical Society.

引用

页码：13368 / 13369

页数：2

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