Preparation of luminescent lanthanide polymers by ring-opening metathesis polymerization

被引：10
|
作者：
Yoon, Myeong Sik [1 ]
Santra, Mithun [2 ,3 ]
Ahn, Kyo Han [2 ,3 ]
机构：
[1] Hoseo Univ, Dept Pharmaceut Engn, Asan 336795, Chungcheongnam, South Korea
[2] POSTECH, Dept Chem, Pohang 790784, Gyungbuk, South Korea
[3] POSTECH, Ctr Electrophoto Behav Adv Mol Syst, Pohang 790784, Gyungbuk, South Korea
来源：
TETRAHEDRON LETTERS | 2015年 / 56卷 / 41期
基金：
新加坡国家研究基金会;
关键词：
Eu(III) complexes; Tb(III) complexes; Lanthanide luminescence; Lanthanide polymers; Ring-opening metathesis polymerization (ROMP); INTRAMOLECULAR ENERGY-TRANSFER; METAL-ORGANIC FRAMEWORK; CRYSTAL-STRUCTURES; COORDINATION POLYMERS; HIGHLY LUMINESCENT; SUPRAMOLECULAR CHEMISTRY; MAGNETIC-PROPERTIES; COMPLEXES; EUROPIUM; SERIES;
D O I：
10.1016/j.tetlet.2015.08.042
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Polymeric lanthanide complexes have been synthesized through ring-opening metathesis polymerization of monomeric lanthanide complexes of pyridine dicarboxylates that contain a norbornene group. The lanthanide monomer complexes, Eu(III) and Tb(III) complexes, have three norbomene groups that allow three-dimensional polymeric networking, and the corresponding polymers of Eu(III), Tb(III), and their equimolar complexes are highly luminescent with intense emission bands in the characteristic visible region. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码：5573 / 5577
页数：5
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