Thioglycuronides:: Synthesis and application in the assembly of acidic oligosaccharides

被引：137

作者：

van den Bos, LJ ^{[1
]}

Codée, JDC ^{[1
]}

van der Toorn, JC ^{[1
]}

Boltje, TJ ^{[1
]}

van Boom, JH ^{[1
]}

Overkleeft, HS ^{[1
]}

van der Marel, GA ^{[1
]}

机构：

[1] Leiden Univ, Leiden Inst Chem, NL-2300 RA Leiden, Netherlands

来源：

ORGANIC LETTERS | 2004年 / 6卷 / 13期

关键词：

D O I：

10.1021/ol049380+

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Partially protected thioglycuronic acids are prepared efficiently by chemo- and regioselective oxidation of the corresponding thioglycosides using the TEMPO/BAIB reagent combination. After esterification, the thioglycuronic acids proved to be useful as both donor and acceptor in sulfonium-mediated condensations toward acidic di- and trisaccharides.

引用

页码：2165 / 2168

页数：4

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