Stereoselective total synthesis of (±)-homochelidonine

被引：14

作者：

Yoshida, M ^{[1
]}

Watanabe, T ^{[1
]}

Ishikawa, T ^{[1
]}

机构：

[1] Chiba Univ, Grad Sch Pharmaceut Sci, Chiba 2638522, Japan

来源：

TETRAHEDRON LETTERS | 2002年 / 43卷 / 38期

关键词：

D O I：

10.1016/S0040-4039(02)01526-5

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(+/-)-Homochelidonine, a B/C-cis-11-hydroxyhexahydrobenzo[c]phenanthridine alkaloid, was stereo selectively synthesized from arnottin II, a non-alkaloidal spirolactonyl tetralone which had been structurally correlated to chelerythrine, a fully aromatized-type alkaloid, by the common use of a 2-benzofuranyl-1-tetralone as a synthetic key intermediate. Thus, a valuable synthetic method accessible to benzo[c]phenanthridine alkaloids with different oxidation stages of the basic skeleton could be proposed. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：6751 / 6753

页数：3

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