Cesium partly substituted salts CsxH6-xP2W18O62 of Wells-Dawson heteropolyacid as catalysts for ethyl-tert-butyl ether synthesis

被引：8
|
作者：
Pozniczek, Joanna
Lubanska, Anna
Mucha, Dariusz
Bielanski, Adam
机构：
[1] Polish Acad Sci, Inst Catalysis & Surface Chem, PL-30239 Krakow, Poland
[2] Jagiellonian Univ, Dept Chem, PL-30060 Krakow, Poland
来源：
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL | 2006年 / 257卷 / 1-2期
关键词：
Dawson; heteropolyacid; cesium salts; ethyl-tert-butyl ether (ETBE);
D O I：
10.1016/j.molcata.2006.04.036
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A series of partly substituted cesium salts Cs1H6-1P2W18O62 of Wells-Dawson heteropolyacid has been prepared. The samples were catalytically active at temperatures as low as 40 degrees C despite low specific surface area of the order of 1 m(2) g(-1). Activity in gas phase synthesis of ethyl-tert-butyl ether related to mass of non-neutralized acid reached maximum at x = 5 and was higher than that of unsupported crystalline heteropolyacid. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：99 / 104
页数：6
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