Synthesis, magneto-spectral and thermal studies of cobalt(II) complexes of 4-[N-(benzalidene)amino] antipyrine thiosemicarbazone and 4-[N-(2′-hydroxybenzalidene)amino] antipyrine thiosemicarbazone

被引：0

作者：

Chakraborti, I ^{[1
]}

机构：

[1] BRA Bihar Univ, LS Coll, Dept Chem, Muzaffarpur 842001, India

来源：

ASIAN JOURNAL OF CHEMISTRY | 2003年 / 15卷 / 03期

关键词：

cobalt(II); chelates; thiosemicarbazone;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reactions of CoX2 (X = Cl, NO3, NCS, CH3COO or ClO4) with 4-[N-(benzalidene)amino]antipyrine thiosemicarbazone (BAAPTS) or 4-[N-(2'-hydroxybenzalidene)amino]antipyrine thiosemicarbazone (HBAAPTS) yielded complexes of the type CoX2.(L)(H2O)-H-. or Co(ClO4)(2)(.)2L (L = BAAPTS or HBAAPTS). The infrared spectra of these complexes indicate that the thiosemicarbazones behave as neutral tridentate (N,N,S) ligands. All the complexes are six-coordinated according to the data of magnetic and electronic spectral measurements.

引用

页码：1795 / 1802

页数：8

共 50 条

[31] Studies on the Effect of Various Anions and Pyridine on the Stereochemistry of Lanthanide(III) Coordination Compounds of 4[N-(2'-Hydroxy-1'-Naphthalidene)Amino] Antipyrine Thiosemicarbazone
Agarwal, Ram K.
Kumar, Vinesh
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2010, 185 (07) : 1469 - 1483
[32] MAGNETO, SPECTRAL AND THERMAL INVESTIGATIONS OF SOME LANTHANIDE(III) COMPLEXES OF 4[-(N-CINNAMALIDENE)AMINO]ANTIPYRINE
AGARWAL, RK
AGARWAL, H
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1995, 25 (05): : 715 - 737
[33] MAGNETIC, SPECTRAL AND THERMAL INVESTIGATIONS OF LANTHANIDE(III) NITRATO AND ISOTHIOCYANATO COMPLEXES OF 4-[(N-4-HYDROXY-3-METHOXYBENZALIDENE)AMINO]-ANTIPYRINE
AGARWAL, RK
SARIN, RK
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1994, 24 (04): : 499 - 517
[34] Synthesis and characterizations of 4-[ (N-Hydroxyethyl-N-Methyl) amino] benzaldehyde thiosemicarbazone and its complexes with transition metals
Hao, FY
Zhang, XJ
Hu, HM
Zhang, ML
Tian, YP
Fun, HK
[J]. CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2001, 17 (04) : 496 - 500
[35] Studies on the thermal decomposition kinetics of 4-[N(3,4,5-trimethoxy benzalidene)amino] antipyrine complexes of thorium(IV) and dioxouranium(VI) nitrates using three different methods
Arora, K
Sinha, P
[J]. OXIDATION COMMUNICATIONS, 1996, 19 (04): : 575 - 581
[36] SYNTHESIS AND CHARACTERIZATION OF THORIUM(IV) AND DIOXOURANIUM(VI) COMPLEXES OF 4-[N(2-HYDROXY-1-NAPHTHALIDENE)AMINO]ANTIPYRINE
AGARWAL, RK
PRAKASH, J
[J]. POLYHEDRON, 1991, 10 (20-21) : 2399 - 2403
[37] SYNTHESIS, SPECTRAL AND THERMAL STUDIES OF SCHIFF BASE COMPLEXES DERIVED FROM N-(4-((2-HYDROXYBENZYLIDENE) AMINO) PHENYL) PYRIDINE-2-SULFONAMIDE
Sadafale, V. A.
[J]. HETEROCYCLIC LETTERS, 2024, 14 (02): : 353 - 361
[38] SYNTHESIS AND CHARACTERIZATION OF THORIUM(IV) AND DIOXOURANIUM(VI) COMPLEXES OF 4-[N(P-DIMETHYL-AMONOBENZALIDENE)AMINO]ANTIPYRINE
AGARWAL, RK
CHAKRAVORTI, I
PRAKASH, J
[J]. POLISH JOURNAL OF CHEMISTRY, 1993, 67 (11) : 1933 - 1945
[39] Chelating behaviour of 4[N-(benzylidene)amino]-antipyrine semicarbazone towards lanthanide ions
Agarwal, RK
Agarwal, H
[J]. SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY, 1996, 26 (07): : 1163 - 1177
[40] Synthesis of some lanthanide(III) complexes derived from 4-[N-(4-methoxybenzylidene)amino]antipyrinethiosemicarbazone
Agarwal, RK
Goel, N
Sharma, AK
[J]. JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2001, 78 (01) : 39 - 40

← 1 2 3 4 5 →