Effect of La2O3 Doping on Conductivity of ZrO2-Sc2O3-CeO2 System

被引:3
|
作者
Barbashov, V. I. [1 ]
Timchenko, V. M. [1 ]
Nesova, E. V. [1 ]
机构
[1] Natl Acad Sci Ukraine, Donetsk Phys Tech Inst, UA-83114 Donetsk, Ukraine
来源
SOLID OXIDE FUEL CELLS 11 (SOFC-XI) | 2009年 / 25卷 / 02期
关键词
D O I
10.1149/1.3205703
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
The effect of La doping on conductivity of ZrO2 - Sc2O3 - CeO2 system was studied. The presence of the hysteresis loop was shown and related to the polymorphic transformation from the orthorhombohedral phase to the cubic phase. 0.5 mol% La2O3 doping replaces the hysteresis loop in a region of high temperatures. The results are discussed in borders of the baric model for the ionic conductivity of zirconium oxide which assumes the control character for the influence of the hydrostatic pressure on the diffusion mobility of oxygen ions.
引用
收藏
页码:1659 / 1664
页数:6
相关论文
共 50 条
  • [1] Preparation and conductivity of Sc2O3-CeO2-ZrO2
    Tan, Jiang
    Su, Yuchang
    Hu, Te
    Yu, Qiushan
    Tursun, Rabigul
    Li, Quan
    Xi, Yunze
    SOLID STATE IONICS, 2016, 292 : 22 - 26
  • [2] Electrical conductivity in the system ZrO2-Y2O3-Sc2O3
    Kanagawa Univ, Yokohama, Japan
    Solid State Ionics, 3-4 (185-189):
  • [3] Electrical conductivity in the system ZrO2-Y2O3-Sc2O3
    Yamamura, H
    Utsunomiya, N
    Mori, T
    Atake, T
    SOLID STATE IONICS, 1998, 107 (3-4) : 185 - 189
  • [4] The electrical conductivity of the ZrO2-Sc2O3-Y2O3 and ZrO2-Sc2O3-Yb2O3 systems
    Arachi, Y
    Yamamoto, O
    Takeda, Y
    Imanishi, N
    DENKI KAGAKU, 1996, 64 (06): : 638 - 641
  • [5] Effect of La2O3 on Ru/CeO2-La2O3 Catalyst for Ammonia Synthesis
    Xiaojun Luo
    Rong Wang
    Jun Ni
    Jianxin Lin
    Bingyu Lin
    Xianming Xu
    Kemei Wei
    Catalysis Letters, 2009, 133 : 382 - 387
  • [6] Effect of La2O3 on Ru/CeO2-La2O3 Catalyst for Ammonia Synthesis
    Luo, Xiaojun
    Wang, Rong
    Ni, Jun
    Lin, Jianxin
    Lin, Bingyu
    Xu, Xianming
    Wei, Kemei
    CATALYSIS LETTERS, 2009, 133 (3-4) : 382 - 387
  • [7] Effect of CeO2 and La2O3 on the Activity of CeO2−La2O3/Al2O3-Supported Pd Catalysts for Steam Reforming of Methane
    W. H. Cassinelli
    L. S. F. Feio
    J. C. S. Araújo
    C. E. Hori
    F. B. Noronha
    C. M. P. Marques
    J. M. C. Bueno
    Catalysis Letters, 2008, 120 : 86 - 94
  • [8] Effect of La2O3 on Grain Refinement and Thermal Conductivity of 6 mol % Y2O3-ZrO2 Fibers
    Yuan, Kangkang
    Jin, Xiaotong
    Wang, Xinqiang
    Zhang, Guanghui
    Zhu, Luyi
    Xu, Dong
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2019, 64 (11) : 1464 - 1468
  • [9] CeO2-ZrO2-La2O3-Al2O3compositeoxideanditssupportedpalladiumcatalystforthetreatmentofexhaustofnaturalgasenginedvehicles
    Xiaoyu Zhang Enyan Long Yile Li Jiaxiu Guo Lijuan Zhang Maochu Gong Minghua Wang Yaoqiang Chen Key Laboratory of Green Chemistry Technology of the Ministry of Education College of Chemistry Sichuan University Chengdu Sichuan China College of Architecture and Environment Sichuan University Chengdu Sichuan China State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences Dalian Liaoning China Sichuan Tianyi Science Technology Co Ltd Chengdu Sichuan China
    Journal of Natural Gas Chemistry, 2009, 18 (02) : 139 - 144
  • [10] THE SC2O3-ZRO2-AL2O3 SYSTEM - ELECTRICAL-CONDUCTIVITY AND MICROSTRUCTURE
    BADWAL, SPS
    DRENNAN, J
    JOURNAL OF THE AUSTRALASIAN CERAMIC SOCIETY, 1984, 20 (02): : 28 - 31