Industrial wastewater advanced oxidation .1. UV radiation in the presence and absence of hydrogen peroxide

被引:79
|
作者
Beltran, FJ
Gonzalez, M
Gonzalez, JF
机构
[1] Depto. de Ing. Quim. y Energetica, Universidad de Extremadura
关键词
distillery wastewaters; tomato wastewaters; advanced oxidation technologies; wastewater treatment; UV radiation;
D O I
10.1016/S0043-1354(97)00077-8
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The oxidation of two wastewaters collected from distillery and tomato processing plants with UV radiation (254 nm) alone and combined with hydrogen peroxide has been investigated. Distillery wastewaters are refractory to UV radiation but the presence of hydrogen peroxide leads to different COD reductions which indicates that the process is mainly due to the action of radicals. Tomato wastewaters, on the other hand, show a higher reactivity even with UV radiation alone. The quantum yield for tomato wastewaters with an initial COD of 930 mg O-2 l(-1) was found to be 0.7 mol O-2 photon(-1) and decreased with reaction time. The combined effect of UV radiation and hydrogen peroxide at a 0.01 M concentration on tomato wastewaters leads to about 25% COD reduction while TOC was unchanged. The contribution of radical reactions in this process was higher than 60%. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:2405 / 2414
页数:10
相关论文
共 50 条
  • [21] CATALYSED HYDROGEN PEROXIDE OXIDATION OF AROMATIC HYDROCARBONS .1.
    COOK, JW
    SCHOENTAL, R
    [J]. JOURNAL OF THE CHEMICAL SOCIETY, 1950, (JAN): : 47 - 54
  • [22] Improvement of the wastewater biodegradability by means of photocatalytic and wet oxidation processes in the presence of hydrogen peroxide
    Genç, N
    Arslan, A
    Can-Dogan, E
    [J]. CHEMICAL AND BIOCHEMICAL ENGINEERING QUARTERLY, 2005, 19 (04) : 391 - 396
  • [23] Catalytic oxidation of the dye wastewater with hydrogen peroxide
    Qiu, ZM
    He, YB
    Liu, XC
    Yu, SX
    [J]. CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2005, 44 (09) : 1013 - 1017
  • [24] Oxidation of dichlorvos by UV/hydrogen peroxide process
    Lu, MC
    Chang, YF
    Chyan, JM
    Liao, CH
    [J]. FRESENIUS ENVIRONMENTAL BULLETIN, 2005, 14 (03): : 199 - 203
  • [26] ADVANCED OXIDATION PROCESSES - A KINETIC-MODEL FOR THE OXIDATION OF 1,2-DIBROMO-3-CHLOROPROPANE IN WATER BY THE COMBINATION OF HYDROGEN-PEROXIDE AND UV-RADIATION
    GLAZE, WH
    LAY, Y
    KANG, JW
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1995, 34 (07) : 2314 - 2323
  • [27] Advanced oxidation process of chlorophenol wastewater by ozone-hydrogen peroxide and its kinetics
    Li, Zhong
    Kuo, C.H.
    [J]. Chung-kuo Tsao Chih/China Pulp and Paper, 2000, 19 (03): : 35 - 39
  • [28] Modeling the UV/hydrogen peroxide advanced oxidation process using computational fluid dynamics
    Alpert, Scott M.
    Knappe, Detlef R. U.
    Ducoste, Joel J.
    [J]. WATER RESEARCH, 2010, 44 (06) : 1797 - 1808
  • [29] Aqueous degradation of VOCs in the ozone combined with hydrogen peroxide or UV radiation processes -: 1.: Experimental results
    Beltrán, FJ
    González, M
    Rivas, J
    Acedo, B
    [J]. JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING, 1999, 34 (03): : 649 - 671
  • [30] Aqueous degradation of VOCs in the ozone combined with hydrogen peroxide or UV radiation processes 1. Experimental results
    Beltrán, Fernando J.
    González, Manuel
    Rivas, Javier
    Acedo, Benito
    [J]. Journal of Environmental Science and Health - Part A Toxic/Hazardous Substances and Environmental Engineering, 1999, 34 (03): : 649 - 671