Hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones

被引:75
|
作者
Uyanik, Muhammet [1 ]
Yasui, Takeshi [1 ]
Ishihara, Kazuaki [1 ]
机构
[1] Nagoya Univ, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
关键词
CHEMISTRY; KETONES; REACTIVITY; OXIDATIONS; REAGENTS;
D O I
10.1016/j.bmcl.2009.03.148
中图分类号
R914 [药物化学];
学科分类号
100701 ;
摘要
The hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones was achieved in the presence of iodobenzene (10 mol %), p-toluenesulfonic acid monohydrate (20 mol %) and meta-chloroperbenzoic acid as a stoichiometric co-oxidant. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码:3848 / 3851
页数:4
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