Line strengths of diatomics: The b(1)Sigma(+)v'=0->X-3 Sigma-v''=0 transition of the NF radical

被引：7

作者：

DiStefano, G ^{[1
]}

Lenzi, M ^{[1
]}

Piciacchia, G ^{[1
]}

Ricci, A ^{[1
]}

机构：

[1] CNR,AREA RIC,I-00016 MONTEROTONDO,ITALY

来源：

JOURNAL OF CHEMICAL PHYSICS | 1997年 / 107卷 / 08期

关键词：

D O I：

10.1063/1.475127

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Line intensities in the (0,0) band of NF(b (1) Sigma+ --> X (3) Sigma(-)) spin forbidden emission have been observed in a microwave apparatus. Deduced line strengths of the P-O and R-S well resolved branches are shown differently, in contrast with the theoretical prevision, and are interpreted by taking into account some peculiarities of the NF radical. An intermediate (a) and (b) Hund case is seen to apply to P-O and R-S in the whole rotational range examined. Accordingly, a reliable value for the effective transition moment mu(e) is evaluated from the experiment, (C) 1997 American Institute of Physics.

引用

页码：2752 / 2759

页数：8

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