Monophasic zircon-type tetragonal Eu1 - xBixVO4 solid-solution: synthesis, characterization, and optical properties

被引：10
|
作者：
Yi, Juan [1 ]
Zhao, Zongyan [1 ]
Wang, Yu'an [2 ]
Zhou, Dacheng [1 ]
Ma, Chenshuo [1 ]
Cao, Yuechan [1 ]
Qiu, Jianbei [1 ]
机构：
[1] Kunming Univ Sci & Technol, Sch Mat Sci & Engn, Kunming 650093, Peoples R China
[2] Shenzhen Water Grp Co Ltd, Shenzhen 518000, Peoples R China
来源：
MATERIALS RESEARCH BULLETIN | 2014年 / 57卷
基金：
中国国家自然科学基金;
关键词：
Optical material; Luminescence; Optical properties; PHOTOLUMINESCENCE PROPERTIES; NANOPARTICLES; LUMINESCENCE; PHOSPHORS; BIVO4; SM;
D O I：
10.1016/j.materresbull.2014.04.068
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
By combining the methods of co-precipitation and hydrothermal synthesis methods, the complete solid-solution of Eu1 - xBixVO4 with monophasic zircon-type structure was successfully synthesized. The zircon-type structure was determined by X-ray diffractometer and Raman scattering, and the optical properties were characterized by ultraviolet-visible diffuse reflectance and photoluminescence spectrophotometer. The results indicate that the band gap of Eu1 - xBixVO4 could be adjusted and controlled by bismuth content in the range of x = 0-0.9. Meanwhile, the Eu1 - xBixVO4 solid-solution phosphors show strong red light emission was shown in 619 nm under both near UV-light and visible-light excitation. Notably, the emission intensity of Eu1 - xBixVO4 (x= 0.4) is the strongest in all samples. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：306 / 310
页数：5
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