Facile One-Pot Synthesis of Diaryliodonium Salts from Arenes and Aryl Iodides with Oxone

被引：15

作者：

Soldatova, Natalia ^{[1
,2
]}

Postnikov, Pavel ^{[1
,2
]}

Kukurina, Olga ^{[1
,2
]}

Zhdankin, Viktor V. ^{[1
,2
,3
]}

Yoshimura, Akira ^{[3
]}

Wirth, Thomas ^{[4
]}

Yusubov, Mekhman S. ^{[1
,2
]}

机构：

[1] Tomsk Polytech Univ, Tomsk 634050, Russia

[2] Siberian State Med Univ, Tomsk 634050, Russia

[3] Univ Minnesota Duluth, Dept Chem & Biochem, Duluth, MN 55812 USA

[4] Cardiff Univ, Sch Chem, Pk Pl,Main Bldg, Cardiff CF10 3AT, Wales

来源：

CHEMISTRYOPEN | 2017年 / 6卷 / 01期

关键词：

diaryliodonium triflates; diaryliodonium trifluoroacetates; iodine(III) compounds; oxidation; synthesis; TRIFLUOROACETIC-ACID; ARYLBORONIC ACIDS; IODINE; DERIVATIVES; OXIDATION; EFFICIENT; VERSATILE; SCOPE;

D O I：

10.1002/open.201600129

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A straightforward synthesis of diaryliodonium salts is achieved by using Oxone as the stoichiometric oxidant. Slow addition is the key to obtaining good yields and purities of the reaction products, which are highly useful reagents in many different areas of organic synthesis.

引用

页码：18 / 20

页数：3

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