Regiospecific one-pot synthesis of diaryliodonium tetrafluoroborates from arylboronic acids and aryl iodides

被引：196
|
作者：
Bielawski, Marcin [1 ]
Aili, David [1 ]
Olofsson, Berit [1 ]
机构：
[1] Stockholm Univ, Dept Organ Chem, Arrhenius Lab, SE-10691 Stockholm, Sweden
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2008年 / 73卷 / 12期
关键词：
D O I：
10.1021/jo8004974
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Diaryliodonium salts have recently received considerable attention as mild arylation reagents in organic synthesis. This paper describes a regiospecific, sequential one-pot synthesis of symmetrical and unsymmetrical diaryliodonium tetrafluoroborates, which are the most popular salts in metal-catalyzed arylations. The protocol is fast and high-yielding and has a large substrate scope. Furthermore, the corresponding diaryliodonium triflates can conveniently be obtained via an in situ anion exchange.
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收藏
页码：4602 / 4607
页数：6
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