Quantification of the chiral recognition in electrochemically driven ion transfer across the interface water/chiral liquid

被引：41

作者：

Scholz, F ^{[1
]}

Gulaboski, R ^{[1
]}

Mirceski, V ^{[1
]}

Langer, P ^{[1
]}

机构：

[1] Ernst Moritz Arndt Univ Greifswald, Inst Chem & Biochem, D-17489 Greifswald, Germany

来源：

ELECTROCHEMISTRY COMMUNICATIONS | 2002年 / 4卷 / 08期

关键词：

chiral recognition; ion transfer; three-phase junction; voltammetry;

D O I：

10.1016/S1388-2481(02)00410-1

中图分类号：

O646 [电化学、电解、磁化学];

学科分类号：

081704 ;

摘要：

The electrochemically driven transfer of the chiral anions of D- and L-tryptophan across the interface water/chiral liquid (D- or L-menthol) is stereoselective, and it can be used to determine quantitatively the difference in Gibbs energies for the solvation of chiral ions in chiral liquids. The ion transfer can be achieved in a three-phase arrangement where a droplet of the chiral liquid containing decamethylferrocene as the electroactive redox probe is attached to a graphite electrode immersed in the aqueous solution containing the chiral ions. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：659 / 662

页数：4

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