A short diastereoselective synthesis of orthogonally protected diaminosuccinic acid derivatives

被引:8
|
作者
Zeitler, K [1 ]
Steglich, W [1 ]
机构
[1] Univ Munich, Dept Chem, D-81377 Munich, Germany
来源
JOURNAL OF ORGANIC CHEMISTRY | 2004年 / 69卷 / 18期
关键词
D O I
10.1021/jo049371e
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Homogeneous, Rh-catalyzed hydrogenation of heteromeric olefinic glycine dimers presents an efficient route to diastereomerically pure, orthogonally protected diaminosuccinic acid derivatives depending on the double bond geometry of the starting material. The products were obtained as racemates.
引用
收藏
页码:6134 / 6136
页数:3
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