A novel two-dimensional MnII coordination polymer with 1,2-bis(imidazol-1-yl)ethane

被引：13

作者：

Li, BL ^{[1
]}

Zhu, X ^{[1
]}

Zhou, JH ^{[1
]}

Zhang, Y ^{[1
]}

机构：

[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104014453

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the crystal structure of the title complex, poly[[diazido-manganese(II)]-di-mu-1,2-bis(imidazol-1-yl)ethane-kappa(4)N(3):N-3'], [Mn(N-3)(2)(C8H10N4)(2)](n) or [Mn(N-3)(2)(bim)(2)](n), where bim is 1,2-bis(imidazol-1-yl) ethane, each Mn-II atom is six-coordinated in a distorted octahedral coordination environment to four N atoms from four bim ligands and two N atoms from two azide ligands. The Mn-II atoms, which lie on inversion centres, are bridged by four bim ligands to form a two-dimensional (4,4)-network. The azide ligands are monodentate (terminal).

引用

页码：M373 / M374

页数：2

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