A novel two-dimensional MnII coordination polymer with 1,2-bis(imidazol-1-yl)ethane

被引：13
|
作者：
Li, BL [1 ]
Zhu, X [1 ]
Zhou, JH [1 ]
Zhang, Y [1 ]
机构：
[1] Suzhou Univ, Coll Chem & Chem Engn, Key Lab Organ Synth Jiangsu Prov, Suzhou 215006, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷
关键词：
D O I：
10.1107/S0108270104014453
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In the crystal structure of the title complex, poly[[diazido-manganese(II)]-di-mu-1,2-bis(imidazol-1-yl)ethane-kappa(4)N(3):N-3'], [Mn(N-3)(2)(C8H10N4)(2)](n) or [Mn(N-3)(2)(bim)(2)](n), where bim is 1,2-bis(imidazol-1-yl) ethane, each Mn-II atom is six-coordinated in a distorted octahedral coordination environment to four N atoms from four bim ligands and two N atoms from two azide ligands. The Mn-II atoms, which lie on inversion centres, are bridged by four bim ligands to form a two-dimensional (4,4)-network. The azide ligands are monodentate (terminal).
引用
收藏
页码：M373 / M374
页数：2
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