Platinum-Catalyzed Hydrosilylation in Polymer Chemistry

被引：70
|
作者：
Lukin, Ruslan Yu. [1 ,2 ]
Kuchkaev, Aidar M. [1 ,2 ]
Sukhov, Aleksandr V. [1 ,2 ]
Bekmukhamedov, Giyjaz E. [1 ,2 ]
Yakhvarov, Dmitry G. [1 ,2 ]
机构：
[1] Kazan Fed Univ, Alexander Butlerov Inst Chem, Kazan 420008, Russia
[2] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, FRC Kazan Sci Ctr, Kazan 420088, Russia
来源：
POLYMERS | 2020年 / 12卷 / 10期
关键词：
silicone polymers; hydrosilylation; organometallic catalysts; platinum complexes; PLATINUM(0)-CARBENE COMPLEXES; ACTIVE CATALYST; MECHANISM; HYDROSILATION; EFFICIENT; LIGANDS; ISOMERIZATION; SILICONE; STYRENES; ALKENES;
D O I：
10.3390/polym12102174
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This paper addresses a review of platinum-based hydrosilylation catalysts. The main field of application of these catalysts is the curing of silicone polymers. Since the 1960s, this area has developed rapidly in connection with the emergence of new polymer compositions and new areas of application. Here we describe general mechanisms of the catalyst activity and the structural effects of the ligands on activity and stability of the catalysts together with the methods for their synthesis.
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页数：22
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