Selective oxidation of glycerol to formic acid in highly concentrated aqueous solutions with molecular oxygen using V-substituted phosphomolybdic acids

被引：37

作者：

Zhang, Jizhe ^{[1
]}

Sun, Miao ^{[2
]}

Han, Yu ^{[1
]}

机构：

[1] King Abdullah Univ Sci & Technol, Phys Sci & Engn Div, Adv Membranes & Porous Mat Ctr, Thuwal 239556900, Saudi Arabia

[2] King Abdullah Univ Sci & Technol, Cooperate Res & Dev Ctr, Thuwal 239556900, Saudi Arabia

来源：

RSC ADVANCES | 2014年 / 4卷 / 67期

关键词：

BIOMASS-DERIVED HYDROCARBONS; HYDROGEN-PRODUCTION; ROOM-TEMPERATURE; BIMETALLIC CATALYSTS; CONVERSION; DECOMPOSITION; STORAGE; WATER; PD; DIHYDROXYACETONE;

D O I：

10.1039/c4ra05424e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Formic acid is an important commodity chemical as well as a promising medium for hydrogen storage and hydrogen production. In this paper, we report that formic acid can be produced through selective oxidation of glycerol, a low-cost by-product of biodiesel, by using vanadium-substituted phosphomolybdic acids as catalysts and molecular oxygen as the oxidant. Significantly, this catalytic system allows for high-concentration conversions and thus leads to exceptional efficiency. Specifically, 3.64 g of formic acid was produced from 10 g of glycerol/water (50/50 in weight) solution.

引用

页码：35463 / 35466

页数：4

共 45 条

[31] Au/Mg(OH)2: Highly efficient for selective oxidation of 1,2-propanediol to lactic acid with molecular oxygen
Hong Ma
Xin Nie
JiaYing Cai
Chen Chen
Jin Gao
Hong Miao
Jie Xu
[J]. Science China Chemistry, 2010, 53 : 1497 - 1501
[32] NITROUS-ACID CATALYSIS OF THE OXIDATION OF BENZYL ALCOHOL BY OXYGEN IN HIGHLY ACIDIC AQUEOUS-SOLUTIONS IN THE PRESENCE OF CHLORIDE-IONS
LEVINA, AB
TRUSOV, SR
[J]. KINETICS AND CATALYSIS, 1992, 33 (01) : 74 - 78
[33] Selective Oxidation of Cyclohexanone to Adipic Acid Using Molecular Oxygen in the Presence of Alkyl Nitrites and Transition Metals as Catalysts
Lisicki, Dawid
Orlinska, Beata
Martyniuk, Tomasz
Dziuba, Krzysztof
Binczak, Jakub
[J]. MATERIALS, 2023, 16 (16)
[34] Selective Methane Oxidation to Acetic Acid Using Molecular Oxygen over a Mono-Copper Hydroxyl Catalyst
Antil, Neha
Chauhan, Manav
Akhtar, Naved
Kalita, Rahul
Manna, Kuntal
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2023, 145 (11) : 6156 - 6165
[35] Selective oxidation of hydrocarbons on V- and/or Co-containing aluminophosphate (MeAPO-5) using molecular oxygen
Concepcion, P
Corma, A
Nieto, JML
PerezPariente, J
[J]. APPLIED CATALYSIS A-GENERAL, 1996, 143 (01) : 17 - 28
[36] Aqueous Oxidation of Sugars into Sugar Acids Using Hydrotalcite-supported Gold Nanoparticle Catalyst under Atmospheric Molecular Oxygen
Tomar, Ravi
Sharma, Jatin
Nishimura, Shun
Ebitani, Kohki
[J]. CHEMISTRY LETTERS, 2016, 45 (07) : 843 - 845
[37] Highly selective and sensitive probes for the detection of Cr(vi) in aqueous solutions using diglycolic acid-functionalized Au nanoparticles
Zhang, Yang
Bai, Ruixi
Zhao, Zhigang
Liao, Qiuxia
Chen, Peng
Guo, Wanghuan
Cai, Chunqing
Yang, Fan
[J]. RSC ADVANCES, 2019, 9 (19) : 10958 - 10965
[38] Highly efficient and selective extraction of Pu(IV) using two alkyl-substituted amides of nitrilo triacetic acid from nitric acid solutions
Karak, Ananda
Mahanty, Bholanath
Mohapatra, Prasanta K.
Egberink, Richard J. M.
Valsala, Thichur P.
Sathe, Darshan B.
Bhatt, Raj B.
Huskens, Jurriaan
Verboom, Willem
[J]. SEPARATION AND PURIFICATION TECHNOLOGY, 2021, 279
[39] Highly selective oxidation of allylic alcohols to alpha,beta-unsaturated aldehydes using Pd cluster catalysts in the presence of molecular oxygen
Kaneda, K
Fujii, M
Morioka, K
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1996, 61 (14): : 4502 - 4503
[40] Selective oxidation of alcohols using novel crystalline Mo-V-O oxide as heterogeneous catalyst in liquid phase with molecular oxygen
Wang, Feng
Ueda, Wataru
[J]. CATALYSIS TODAY, 2009, 144 (3-4) : 358 - 361

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