Synthesis and characterization of Ru(II) and Ir(III) complexes that bear camphoric 1,3-diamine ligands

被引：9
|
作者：
Yu, Jun-Lai [1 ]
Guo, Rong [1 ]
Wang, Hui [1 ]
Li, Zhan-Ting [1 ]
Zhang, Dan-Wei [1 ]
机构：
[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 768卷
基金：
中国国家自然科学基金;
关键词：
Ruthenium(II) complex; Iridium(III) complex; Camphoric 1,3-diamine ligand; ASYMMETRIC TRANSFER HYDROGENATION; COPPER(II) COMPLEXES; IRIDIUM COMPLEXES; METAL-COMPLEXES; DIAMINE LIGANDS; CATALYST; KETONES; TRIMETHYLSILYLCYANATION; SILYLCYANATION; INTERMEDIATE;
D O I：
10.1016/j.jorganchem.2014.06.017
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two rigid N-monosulfonylated 1,3-diamine ligands have been prepared starting from commercially available D-camphor through three steps. Their reactions with [Ru(eta(6)-arene)(mu-Cl)Cl](2) (arene = p-cymene or C6H5CO2Et) or [Ir(eta(5)-C5Me5)(mu-Cl)Cl](2) afforded five new complexes. The structures of one monosulfonamide 1,3-diamine ligand and three organometallic complexes were confirmed by X-ray crystallography. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：36 / 41
页数：6
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