Synthesis and characterization of Ru(II) and Ir(III) complexes that bear camphoric 1,3-diamine ligands

被引：9

作者：

Yu, Jun-Lai ^{[1
]}

Guo, Rong ^{[1
]}

Wang, Hui ^{[1
]}

Li, Zhan-Ting ^{[1
]}

Zhang, Dan-Wei ^{[1
]}

机构：

[1] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2014年 / 768卷

基金：

中国国家自然科学基金;

关键词：

Ruthenium(II) complex; Iridium(III) complex; Camphoric 1,3-diamine ligand; ASYMMETRIC TRANSFER HYDROGENATION; COPPER(II) COMPLEXES; IRIDIUM COMPLEXES; METAL-COMPLEXES; DIAMINE LIGANDS; CATALYST; KETONES; TRIMETHYLSILYLCYANATION; SILYLCYANATION; INTERMEDIATE;

D O I：

10.1016/j.jorganchem.2014.06.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two rigid N-monosulfonylated 1,3-diamine ligands have been prepared starting from commercially available D-camphor through three steps. Their reactions with [Ru(eta(6)-arene)(mu-Cl)Cl](2) (arene = p-cymene or C6H5CO2Et) or [Ir(eta(5)-C5Me5)(mu-Cl)Cl](2) afforded five new complexes. The structures of one monosulfonamide 1,3-diamine ligand and three organometallic complexes were confirmed by X-ray crystallography. (C) 2014 Elsevier B.V. All rights reserved.

引用

页码：36 / 41

页数：6

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