Electrochemical synthesis and characterization of conducting polymers in supercritical carbon dioxide

被引：27
|
作者：
Anderson, PE [1 ]
Badlani, RN [1 ]
Mayer, J [1 ]
Mabrouk, PA [1 ]
机构：
[1] Northeastern Univ, Dept Chem, Boston, MA 02115 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 35期
关键词：
D O I：
10.1021/ja026494c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This contribution reports the first synthesis of conducting polymers (CPs), specifically, polyaniline (PAn) and polypyrrole (PPy), in supercritical carbon dioxide (scCO2). CPs synthesized electrochemically in scCO2 were characterized with cyclic voltammetry (CV), four-point probe conductivity, scanning electron microscopy (SEM), and UV-vis spectroscopy. Preliminary data indicate that CPs synthesized by this method exhibit novel morphology and high conductivity comparable to that synthesized by traditional methods. Copyright © 2002 American Chemical Society.
引用
收藏
页码：10284 / 10285
页数：2
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