Photoisomerization of 5,5-dimethyl-3-(3,3-dimethylbut-1-ynyl)-2-(pent-4-enyl)-cyclohex-2-enone to tert-butyl(4,4-dimethyl-2-oxotricyclo[7.3.0.0(1,6)]dodec-6-en-7-yl)carbene

被引：1

作者：

Kisilowski, B

Agosta, WC

Margaretha, P

机构：

[1] UNIV HAMBURG,INST ORGAN CHEM,D-20146 HAMBURG,GERMANY

[2] ROCKEFELLER UNIV,LABS,NEW YORK,NY 10021

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 17期

关键词：

D O I：

10.1039/cc9960002065

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

On irradiation (lambda > 340 nm) cyclohexenone 1 is converted to a mixture of diastereoisomeric 4,4-dimethyl-7-(2,2-dimethylcyclopropyl)tricyclo [7.3.0.0(1,6)] dodec-6-en-2-ones 2 via the title carbene 4, which can also be efficiently trapped both by methanol or by oxygen to afford methyl ethers 5a and 5b or the pivaloyl derivative 6, respectively.

引用

页码：2065 / 2065

页数：1

共 50 条

[41] A New Thermally-stable Insensitive High Explosive: N,N′-Bis(1,2,3,4-tetrazol-5-yl)-4,4′-diamino-2,2′,3,3′,5,5′,6,6′-oetanitroazobenzene (BTeDAONAB)
Mousavi, Sajjad
Esmaeilpour, Karim
Keshavarz, Mohammad Hossein
CENTRAL EUROPEAN JOURNAL OF ENERGETIC MATERIALS, 2013, 10 (04): : 455 - 465
[42] (E)-3,3 ',4,4 ',7,7 ',8,8 '-Octamethyl-2H,2 ' H-1,1 '-bi(cyclopenta[fg]acenaphthylenylidene)-2,2 ',5,5 ',6,6 '-hexaone dichloromethane monosolvate
McCandless, Gregory T.
Sygula, Andrzej
Rabideau, Peter W.
Watkins, Steven F.
Fronczek, Frank R.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1458 - +
[43] 5-tert-butyl-3-{[6-(2,2-dimethyl-1,3-dioxolan-4-yl)-2,2-dimethyltetrahydrofuro[3,4-d][1,3]-dioxol-4-yloxy]methyl}-2-hydroxybenzaldehyde
Zhao, Shan-Shan
Zhao, Ji-Quan
Li, Jian-Xun
Wang, Qian
Zhao, Dong-Min
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2006, 62 : O3372 - O3373
[44] CRYSTAL-STRUCTURE OF 3,3A',5,5'-TETRA-TERT-BUTYL-2'-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)-7'-[1-(3,5-DI-TERT-BUTYL-4-HYDROXYPHENYL)ETHYLIDENE]-3A',4',7',7A'-TETRAHYDROSPIRO[CYCLOHEXA-2,5-DIENE-1,1'-[1H]INDENE]-4,4'-DIONE
HALL, SR
RASTON, CL
WHITE, AH
AUSTRALIAN JOURNAL OF CHEMISTRY, 1980, 33 (02) : 295 - 302
[45] Photooxidation of 2-(tert-Butyl)-3-Methyl-2,3,5,6,7,8-Hexahydroquinazolin-4(1H)-one, an Example of Singlet Oxygen ene Reaction
Mendez, Adrian
Valdez-Camacho, Jonathan Roman
Escalante, Jaime
MOLECULES, 2020, 25 (21):
[46] One-Pot, Three-Component Synthesis of 3-(5-Amino-1H-pyrazol-4-yl)-3-(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-enyl)indolin-2-ones
Ahadi, Somayeh
Mirzaei, Peiman
Bazgir, Ayoob
SYNTHETIC COMMUNICATIONS, 2010, 40 (08) : 1224 - 1230
[47] New route for synthesis, spectroscopy, and X-ray studies of 2-[aryl-(6′-hydroxy-4′,4′-dimethyl-2′-oxocyclohex-6′-enyl)methyl]-3-hydroxy-5,5-dimethylcyclohex-2-enone and 1,8-dioxo-octahydroxanthenes and antitumor evaluation
Fatima Al-Omran
Rafat M. Mohareb
Adel Abou El-Khair
Medicinal Chemistry Research, 2014, 23 : 1623 - 1633
[48] New route for synthesis, spectroscopy, and X-ray studies of 2-[aryl-(6′-hydroxy-4′,4′-dimethyl-2′-oxocyclohex-6′-enyl)methyl]-3-hydroxy-5,5-dimethylcyclohex-2-enone and 1,8-dioxo-octahydroxanthenes and antitumor evaluation
Al-Omran, Fatima
Mohareb, Rafat M.
Abou El-Khair, Adel
MEDICINAL CHEMISTRY RESEARCH, 2014, 23 (04) : 1623 - 1633
[49] Ethyl 5-amino-1-(4-chlorophenyl-5,5-dimethyl-2-oxo-1,3,2-dioxaphosphinan-2-yl)-3-(6-chloro-3-pyridylmethylamino)-1H-pyrazole-4-carboxylate
Luo, ZG
Shi, DQ
Meng, XG
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : O3307 - O3309
[50] 6-Hydroxy-5-[(2-hydroxy-4,4-dimethyl-6-oxocyclohex-1-enyl)(4-nitrophenyl)-methyl]-1,3-dimethylpyrimidine-2,4(1H,3H)-dione
Sureshbabu, N.
Sughanya, V.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : O1690 - +

← 1 2 3 4 5 →