The Electron-Transfer Rate Processes In Biological Systems

被引：0

作者：

Zhu, Hanjun ^{[1
]}

Bai, Tong-Chun ^{[2
]}

Wei, Dongqing ^{[3
]}

机构：

[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11796 USA

[2] Suzhou Univ, Dept Chem, Suzhou, Peoples R China

[3] Shanghai Jiao Tong Univ, Dept Bioinformix, Shanghai, Peoples R China

来源：

THEORY AND APPLICATIONS OF COMPUTATIONAL CHEMISTRY - 2008 | 2009年 / 1102卷

关键词：

Biological Electron Transfer Rate; CHARGE-TRANSFER; POLAR-SOLVENTS; FREE-ENERGY; DYNAMICS; QUANTUM;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reaction coordinates for the electron transfer (ET) reactions are discussed. The channel-based reaction-diffusion equations are solved analytically for two biological electron transfer models, which allow us build an ET rate constant which modifies the Marcus-Jortner formula by adding a dynamic correction factor. The dynamic correction factor can reduce the ET rate by orders of magnitude. The theory has been compared with experiment with fairly good result.

引用

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页码：244 / +

页数：2

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