The Electron-Transfer Rate Processes In Biological Systems

被引：0
|
作者：
Zhu, Hanjun [1 ]
Bai, Tong-Chun [2 ]
Wei, Dongqing [3 ]
机构：
[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11796 USA
[2] Suzhou Univ, Dept Chem, Suzhou, Peoples R China
[3] Shanghai Jiao Tong Univ, Dept Bioinformix, Shanghai, Peoples R China
来源：
THEORY AND APPLICATIONS OF COMPUTATIONAL CHEMISTRY - 2008 | 2009年 / 1102卷
关键词：
Biological Electron Transfer Rate; CHARGE-TRANSFER; POLAR-SOLVENTS; FREE-ENERGY; DYNAMICS; QUANTUM;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction coordinates for the electron transfer (ET) reactions are discussed. The channel-based reaction-diffusion equations are solved analytically for two biological electron transfer models, which allow us build an ET rate constant which modifies the Marcus-Jortner formula by adding a dynamic correction factor. The dynamic correction factor can reduce the ET rate by orders of magnitude. The theory has been compared with experiment with fairly good result.
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页码：244 / +
页数：2
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