Synthesis and electrochemical properties of lithium molybdenum oxides

被引：28
|
作者：
Kobayashi, H
Tabuchi, M
Shikano, M
Nishimura, Y
Kageyama, H
Ishida, T
Nakamura, H
Kurioka, Y
Kanno, R
机构：
[1] MITI, AIST, Osaka Natl Res Inst, Ikeda, Osaka 5638577, Japan
[2] Kinki Univ, Fac Sci & Technol, Dept Elect Engn, Osaka 5778502, Japan
[3] Kobe Univ, Fac Sci, Dept Chem, Kobe, Hyogo 6578501, Japan
来源：
JOURNAL OF POWER SOURCES | 1999年 / 81卷
关键词：
lithium deintercalation; layered oxide; molybdenum oxide;
D O I：
10.1016/S0378-7753(98)00227-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Layered oxides Li2MoO3 were synthesized at 923 K (sample A), 1023 K (sample B), and 1073 K (sample C) and characterized by X-ray diffractometry, magnetic and electrochemical measurements. All Li2MoO3 showed rhombohedral symmetry with an alpha-NaFeO2-related structure and paramagnetic behavior down to 83 K. Lithium. deintercalation from samples B and C proceeded to x=1.2 in Li2-xMoO3. The Li/Li2MoO3 (samples B and C) cells showed cycling capacities of 150 mAh/g in the voltage range of 1.5-4.3 V after 10 cycles. Samples B and C showed better cycle reversibility than sample A. The different charge and discharge characteristics between samples A-C might be caused by structural differences which were indicated by X-ray diffraction measurements. (C) 1999 Elsevier Science S.A. All rights reserved.
引用
收藏
页码：524 / 529
页数：6
相关论文
共 50 条
  • [31] Combinatorial electrochemical synthesis and characterization of tungsten-molybdenum mixed metal oxides
    Sung Hyeon Baeck
    Eric W. McFarland
    Korean Journal of Chemical Engineering, 2002, 19 : 593 - 596
  • [32] Combinatorial electrochemical synthesis and characterization of tungsten-molybdenum mixed metal oxides
    Baeck, SH
    McFarland, EW
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2002, 19 (04) : 593 - 596
  • [33] Synthesis and electrochemical properties of lithium iron phosphate
    Smirnov, K. S.
    Yashtulov, N. A.
    Kuz'micheva, G. M.
    Zhorin, V. A.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2011, 84 (10) : 1744 - 1747
  • [34] Synthesis and electrochemical properties of lithium iron phosphate
    K. S. Smirnov
    N. A. Yashtulov
    G. M. Kuz’micheva
    V. A. Zhorin
    Russian Journal of Applied Chemistry, 2011, 84 : 1744 - 1747
  • [35] Synthesis and electrochemical properties of some lithium chelatophosphates
    Eberwein, M
    Schmid, A
    Schmidt, M
    Zabel, M
    Burgemeister, T
    Barthel, J
    Kunz, W
    Gores, HJ
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2003, 150 (07) : A994 - A999
  • [36] Electrochemical synthesis of new substituted manganese oxides for lithium battery applications
    Machefaux, E.
    Verbaere, A.
    Guyomard, D.
    JOURNAL OF POWER SOURCES, 2006, 157 (01) : 443 - 447
  • [37] INSERTION OF LITHIUM INTO VANADIUM MOLYBDENUM OXIDES.
    Muranushi, Yoshihisa
    Miura, Takashi
    Kishi, Tomiya
    Nagai, Takashi
    1600, (20): : 3 - 4
  • [38] Lithium intercalation studies in hydrated molybdenum oxides
    Guzman, G
    Yebka, B
    Livage, J
    Julien, C
    SOLID STATE IONICS, 1996, 86-8 : 407 - 413
  • [39] LITHIUM INTERCALATION INTO MIXED VANADIUM MOLYBDENUM OXIDES
    WEST, K
    ZACHAUCHRISTIANSEN, B
    SKAARUP, S
    JACOBSEN, T
    SOLID STATE IONICS, 1992, 53 : 356 - 363
  • [40] Vanadium oxides nanostructures: Hydrothermal synthesis and electrochemical properties
    Mjejri, I.
    Etteyeb, N.
    Sediri, F.
    Materials Research Bulletin, 2014, 60 : 97 - 104
12345