From carbon dioxide to methane: Homogeneous reduction of carbon dioxide with hydrosilanes catalyzed by zirconium-borane complexes

被引：200
|
作者：
Matsuo, Tsukasa [1 ]
Kawaguchi, Hiroyuki [1 ]
机构：
[1] Inst Mol Sci, Coordinat Chem Labs, Okazaki, Aichi 4448787, Japan
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2006年 / 128卷 / 38期
关键词：
D O I：
10.1021/ja0647250
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A mixture of a zirconium benzyl phenoxide complex and tris(pentafluorophenyl)borane is reported that catalyzes the hydrosilation reaction of carbon dioxide to generate methane via a bis(silyl)acetal intermediate. Copyright © 2006 American Chemical Society.
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收藏
页码：12362 / 12363
页数：2
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