Synthesis and structures of monomeric group 14 triols and their reactivity

被引：11

作者：

Pop, Lucian-Cristian ^{[1
,2
]}

Kurokawa, Nobuaki ^{[1
]}

Ebata, Hiroaki ^{[1
]}

Tomizawa, Katsuya ^{[1
]}

Tajima, Tomoyuki ^{[1
]}

Ikeda, Masatoshi ^{[1
]}

Yoshioka, Michikazu ^{[1
]}

Biesemans, Monique ^{[3
]}

Willem, Rudolph ^{[3
]}

Minoura, Mao ^{[4
]}

Saito, Masaichi ^{[1
]}

机构：

[1] Saitama Univ, Grad Sch Sci & Engn, Dept Chem, Sakura Ku, Saitama 3388570, Japan

[2] Univ Babes Bolyai, R-3400 Cluj Napoca, Romania

[3] Vrije Univ Brussel, Dept Mat & Chem, High Resolut NMR Ctr, B-1050 Brussels, Belgium

[4] Rikkyo Univ, Coll Sci, Dept Chem, Toshima Ku, Tokyo 1718501, Japan

来源：

CANADIAN JOURNAL OF CHEMISTRY | 2014年 / 92卷 / 06期

关键词：

stannanetriol; germanetriol; silicone grease; cyclostannasiloxane; SOLID-STATE; CRYSTAL-STRUCTURES; SILICONE GREASE; METALLASILOXANES; COMPLEXES; LIGAND; STANNASILOXANES; COORDINATION; SILANETRIOLS; RADII;

D O I：

10.1139/cjc-2013-0496

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first stable stannanetriol and germanetriol bearing sterically congested aryl groups were synthesized by hydrolysis of the corresponding trichloro-stannane and -germane. The stannanetriol is monomeric in solution as well as in the crystalline state, as evidenced by X-ray diffraction analysis and CP-MAS NMR spectroscopy. The stannanetriol reacted with silicone grease to afford a cagelike compound having three Sn-O-Si-O-Sn linkages in the molecule. All the group 14 triols can be converted to the corresponding trihalo compounds in good yields.

引用

页码：542 / 548

页数：7

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