Elemental fluorine .7. New oxidation methodology

被引:7
|
作者
Chambers, RD
Hutchinson, J
Sandford, G
Shah, A
Vaughan, JFS
机构
[1] Department of Chemistry, University of Durham, Durham DH1 3LE, South Road
关键词
D O I
10.1016/S0040-4020(97)10043-6
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Reaction of fluorine with water in the presence of acids provides new oxidants for 'in-situ' oxidation of ketones. Direct reaction of fluorine with anhydrous alcohols and 1,2-diols provides simple methodology for oxidation to corresponding secondary ketones or alpha-hydroxy ketones. (C) 1997 Elsevier Science Ltd.
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页码:15833 / 15842
页数:10
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