Fabrication of Electrically Conductive Metal Patterns at the Surface of Polymer Films by Microplasma-Based Direct Writing

被引：35
|
作者：
Ghosh, Souvik [1 ]
Yang, Rui [2 ]
Kaumeyer, Michelle [2 ]
Zorman, Christian A. [2 ]
Rowan, Stuart J. [3 ]
Feng, Philip X. -L. [2 ]
Sankaran, R. Mohan [1 ]
机构：
[1] Case Western Reserve Univ, Dept Chem Engn, Cleveland, OH 44106 USA
[2] Case Western Reserve Univ, Dept Elect Engn & Comp Sci, Cleveland, OH 44106 USA
[3] Case Western Reserve Univ, Dept Macromol Sci & Engn, Cleveland, OH 44106 USA
来源：
ACS APPLIED MATERIALS & INTERFACES | 2014年 / 6卷 / 05期
基金：
美国国家科学基金会;
关键词：
microplasma; direct write; electrodiffusion; printed electronics; flexible electronics; sheet resistance; ROLL-TO-ROLL; POLY(ACRYLIC ACID); NANOPARTICLES; FEATURES; INKJET;
D O I：
10.1021/am406005a
中图分类号：
TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
We describe a direct-write process for producing electrically conductive metal patterns at the surface of polymers. Thin films of poly(acrylic acid) (PAA) loaded with Ag ions are reduced by a scanning, atmospheric-pressure microplasma to form crystalline Ag features with a line width of 300 mu m. Materials analysis reveals that the metallization occurs in a thin layer of similar to 5 mu m near the film surface, suggesting that, the Ag ions diffuse to the surface. Sheet resistances of 1-10 Omega/sq are obtained independent of film thickness and Ag volume concentration, which is desirable for producing surface conductivity on polymers while minimizing metal loading.
引用
收藏
页码：3099 / 3104
页数：6
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