IBS-Catalyzed Oxidative Rearrangement of Tertiary Allylic Alcohols to Enones with Oxone

被引：75

作者：

Uyanik, Muhammet ^{[1
]}

Fukatsu, Ryota ^{[1
]}

Ishihara, Kazuaki ^{[1
]}

机构：

[1] Nagoya Univ, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan

来源：

ORGANIC LETTERS | 2009年 / 11卷 / 15期

关键词：

HYPERVALENT IODINE REAGENTS; 2-IODOXYBENZENESULFONIC ACID; POLYVALENT IODINE; TRANSPOSITION; ROUTE; CYCLOPENTENONES; ALKALOIDS; CHEMISTRY; ALDEHYDES; PHENOLS;

D O I：

10.1021/ol9013188

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A 2-iodoxybenzenesulfonic acid (IBS)-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with powdered Oxone in the presence of potassium carbonate and tetrabutylammonium hydrogen sulfate has been developed.

引用

页码：3470 / 3473

页数：4

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