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IBS-Catalyzed Oxidative Rearrangement of Tertiary Allylic Alcohols to Enones with Oxone

被引：75
|
作者：
Uyanik, Muhammet [1 ]
Fukatsu, Ryota [1 ]
Ishihara, Kazuaki [1 ]
机构：
[1] Nagoya Univ, Grad Sch Engn, Chikusa Ku, Nagoya, Aichi 4648603, Japan
来源：
ORGANIC LETTERS | 2009年 / 11卷 / 15期
关键词：
HYPERVALENT IODINE REAGENTS; 2-IODOXYBENZENESULFONIC ACID; POLYVALENT IODINE; TRANSPOSITION; ROUTE; CYCLOPENTENONES; ALKALOIDS; CHEMISTRY; ALDEHYDES; PHENOLS;
D O I：
10.1021/ol9013188
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A 2-iodoxybenzenesulfonic acid (IBS)-catalyzed oxidative rearrangement of tertiary allylic alcohols to enones with powdered Oxone in the presence of potassium carbonate and tetrabutylammonium hydrogen sulfate has been developed.
引用
收藏
页码：3470 / 3473
页数：4
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