Metal-free boron-doped graphene for selective electroreduction of carbon dioxide to formic acid/formate

被引：232

作者：

Sreekanth, Narayanaru ^{[1
]}

Nazrulla, Mohammed Azeezulla ^{[2
]}

Vineesh, Thazhe Veettil ^{[1
]}

Sailaja, Krishnamurty ^{[2
]}

Phani, Kanala Lakshminarasimha ^{[1
]}

机构：

[1] CSIR Cent Electrochem Res Inst, Elect & Electrocatalysis Div, Nanoscale Electrocatalysis Grp, Karaikkudi 630006, Tamil Nadu, India

[2] CSIR Cent Electrochem Res Inst, Funct Mat Div, Karaikkudi 630006, Tamil Nadu, India

来源：

CHEMICAL COMMUNICATIONS | 2015年 / 51卷 / 89期

关键词：

SCANNING ELECTROCHEMICAL MICROSCOPY; CO2; REDUCTION; CONVERSION; EFFICIENT; METHANOL; FORMATE; MODE;

D O I：

10.1039/c5cc06051f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Herein we report the electrocatalytic activity of boron-doped graphene for the reduction of CO2. Electrolysis takes place at low overpotentials leading exclusively to formate as the product (vis-a-vis benchmark Bi catalyst). Computational studies reveal mechanistic details of CO2 adsorption and subsequent conversion to formic acid/formate.

引用

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页码：16061 / 16064

页数：4

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