Tungsten CMP: Reduction behavior of iodate ion on tungsten

被引:0
|
作者
Anik, M [1 ]
Osseo-Asare, K [1 ]
机构
[1] Penn State Univ, Dept Mat Sci & Engn, University Pk, PA 16802 USA
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中图分类号
TP3 [计算技术、计算机技术];
学科分类号
0812 ;
摘要
Potentiodynamic polarization was used to study the reduction behavior of iodate ion (IO3-) on tungsten (W) Oxide film formation on W was found to be accelerated considerably in the presence of IO3-. The rate of reduction of IO3- was observed to be controlled by the transfer of H+ to the electrode surface. Tungsten dissolution rate under CMP conditions was predicted with the aid of mixed potential theory. At pH 4 the polishing rate was predicted to increase as the IO3- concentration increased. In contrast, at pH 2, the polishing rate was predicted to be independent of IO3- concentration.
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页码:354 / 360
页数:5
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