Chiral N-tert-Butylsulfinyl Imines: New Discoveries

被引：25
|
作者：
Foubelo, Francisco [1 ,2 ,3 ]
Yus, Miguel [3 ]
机构：
[1] Univ Alicante, Dept Quim Organ, Apdo 99, Alicante 03080, Spain
[2] Univ Alicante, Inst Sintesis Organ ISO, Apdo 99, Alicante 03080, Spain
[3] Univ Alicante, Ctr Innovac Quim Avanzada ORFEO CINQA, Apdo 99, Alicante 03080, Spain
来源：
CHEMICAL RECORD | 2021年 / 21卷 / 06期
关键词：
N-tert-butylsulfinyl imines; organoalkaline compounds; Grignard reagents; organozinc reagents; organoboron compounds; organoaluminum derivatives; organoindium and organosilicon compounds; ASYMMETRIC TRANSFER HYDROGENATION; PROMOTED DIASTEREOSELECTIVE ADDITION; ENANTIOMERICALLY ENRICHED AMINES; ONE-POT SYNTHESIS; STEREOSELECTIVE TOTAL-SYNTHESIS; METHYLENE-GAMMA-BUTYROLACTAMS; INDIUM-MEDIATED ALLYLATION; CONCISE TOTAL SYNTHESES; FORMAL TOTAL-SYNTHESIS; BUTANESULFINYL IMINES;
D O I：
10.1002/tcr.202000122
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
In this account the reactions of chiral N-tert-butylsulfinyl imines with organometallic reagents such as organoalkaline (lithium, sodium, potassium and cesium derivatives), organomagnesium, organozinc, organoboron, organoaluminium, organoindium and organosilicon compounds is comprehensively described. The reactivity in all cases is derived to synthetic applications in order to prepare interesting organic nitrogenated molecules, especially in the field of alkaloid compounds.
引用
收藏
页码：1300 / 1341
页数：42
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