Crystal and molecular structure of antimony thiourea bromide

被引：0
|
作者：
Shettigar, V [1 ]
Bhat, SG [1 ]
Dharmaprakash, SM [1 ]
机构：
[1] Mangalore Univ, Dept Phys, Mangalagangothri 574199, India
来源：
INDIAN JOURNAL OF PURE & APPLIED PHYSICS | 2004年 / 42卷 / 08期
关键词：
crystal and molecular structure; antimony thiourea bromide; non-linear opticals;
D O I：
暂无
中图分类号：
O4 [物理学];
学科分类号：
0702 ;
摘要：
The structure of antimony thiourea bromide hydrate (ATB) with molecular formula Sb[SC(NH2)(2)](2)Br-3.H2O has been determined by X-ray single crystal diffraction. ATB crystallizes in the orthorhombic system with the lattice parameters a = 12.272(3)Angstrom; b = 11.675(4)Angstrom; c = 18.617(5)Angstrom; the space group is Cmc2(l), Z = 8, and Dc = 2.648Mg/m(3). The final R = 0.0366 (wR = 0.0914) for 1273 reflections. The asymmetric unit consists of two symmetrically independent halves of a complex Sb[SC(NH2)(2)](2)Br-3] and one crystal water molecule which are completed to a complex dimer by the mirror plane of the space group. The whole crystal is found packed in mm2 point group, which is non-centrosymnietric arrangement of atoms.
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页码：581 / 584
页数：4
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