Physicochemical Properties of Aqueous Hydroxylamine Sulfate and Aqueous (Hydroxylamine Sulfate plus Ammonium Sulfate) Solutions at Different Temperatures

被引:5
|
作者
Fang, Sheng [1 ]
Zhang, Jian-Guo [2 ]
Liu, Jian-Qing [2 ]
Liu, Ming [1 ]
Luo, Sheng [2 ]
He, Chao-Hong [1 ]
机构
[1] Zhejiang Univ, Dept Chem Engn, Hangzhou 310027, Peoples R China
[2] Quzhou Jinhua Chem Co Ltd, Quzhou 324004, Peoples R China
来源
关键词
ALKALINE ALUMINATE SOLUTIONS; BINARY-MIXTURES; DENSITIES; VISCOSITIES; 25-DEGREES-C; CYCLOHEXANE; CHLORIDE;
D O I
10.1021/je8008649
中图分类号
O414.1 [热力学];
学科分类号
摘要
The densities of an aqueous solution of pure hydroxylamine sulfate at T = (283.15, 288.15, 293.15, 298.15, 303.15, 308.15, and 313.15) K and a solution of hydroxylamine sulfate containing ammonium sulfate at T = (293.15, 298.15, 303.15, 308.15, and 313.15) K have been determined over a wide range of concentrations. The viscosities of binary and ternary mixtures of these compounds at T = (298.15, 303.15, and 308.15) K are also presented. The Masson-type equation and extended Jones-Dole equation in terms of ionic strength are used to correlate the. density and viscosity, respectively, of aqueous solutions of hydroxylamine sulfate. The ideal mixing rule of Young has been successfully applied to predict the ternary densities and viscosities of aqueous hydroxylamine sulfate + ammonium sulfate based on relevant binary solution properties.
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页码:2028 / 2032
页数:5
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