Steroid compounds from the starfish Lysastrosoma anthosticta collected in the Sea of Japan

被引：8
|
作者：
Levina, EV [1 ]
Andriyashchenko, PV [1 ]
Kalinovsky, AI [1 ]
Dmitrenok, PS [1 ]
Stonik, VA [1 ]
Prokof'eva, NG [1 ]
机构：
[1] Russian Acad Sci, Pacific Inst Bioorgan Chem, Far Eastern Branch, Vladivostok 690022, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2002年 / 51卷 / 03期
关键词：
starfish; Lysastrosoma anthosticta; polyhydroxysteroids; sulfated polyols and glycosides; H-1 and C-13 NMR spectroscopy;
D O I：
10.1023/A:1015533024176
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Six polyhydroxylated steroids and their derivatives were isolated from the starfish Lysastrosoma anthosticta collected in the Posyet Bay, Sea of Japan. These include a new glycoside of the steroid polyol, lysastroside A (1), which was identified as (25S)-26-O-beta-D-xylo-pyranosyl-5alpha-cholestane-3beta,6alpha,8,15beta, 16beta,26-hexaol, and the previously known pycnopodioside C monoglycoside (2), marthasterone sulfate (3), (25,S)-5alpha-cholestane-3beta,6alpha,8,15alpha,16beta,26-heptaol (4), (25S)-5alpha-cholestane-3beta,6alpha,7alpha,8,15alpha,16beta,26-heptaol (5), and (25S)-5alpha-cholestane-3beta,6alpha,7alpha,8,15alpha,16beta,26-heptaol (6). The compounds were tested for the haemolytic activity and the action on the embryogenesis of the sea urchin Strongylocentrotus intermedius.
引用
收藏
页码：535 / 539
页数：5
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