One-dimensional hydrogen atom

被引:36
|
作者
Loudon, Rodney [1 ]
机构
[1] Univ Essex, Sch Comp Sci & Elect Engn, Colchester CO4 3SQ, Essex, England
关键词
Coulomb potential; singular and cut-off forms; high magnetic fields; semiconductor quantum wires; carbon nanotubes; polymer chains; MAGNETIC-FIELD; CONJUGATED POLYMERS; DOPED TRANSPOLYACETYLENE; IMPURITY STATES; EXCITONS; SPECTROSCOPY; SEMICONDUCTORS; POLYSILANES; NANOTUBES;
D O I
10.1098/rspa.2015.0534
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The theory of the one-dimensional (1D) hydrogen atom was initiated by a 1952 paper but, after more than 60 years, it remains a topic of debate and controversy. The aim here is a critique of the current status of the theory and its relation to relevant experiments. A 1959 solution of the Schrodinger equation by the use of a cut-off at x=a to remove the singularity at the origin in the 1/broken vertical bar x broken vertical bar form of the potential is clarified and a mistaken approximation is identified. The singular atom is not found in the real world but the theory with cut-off has been applied successfully to a range of four practical three-dimensional systems confined towards one dimension, particularly their observed large increases in ground state binding energy. The true 1D atom is in principle restored when the short distance a tends to zero but it is sometimes claimed that the solutions obtained by the limiting procedure differ from those obtained by solution of the basic Schrodinger equation without any cut-off in the potential. The treatment of the singularity by a limiting procedure for applications to practical systems is endorsed.
引用
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页数:14
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