(2RS)-3-Hydroxy-2-methyl-2-(2-pyridyl)imidazolidine-4-one

被引:7
|
作者
Iskenderov, Turganbay S. [2 ]
Golenya, Irina A. [3 ]
Gumienna-Kontecka, Elzbieta [4 ]
Fritsky, Igor O. [3 ]
Prisyazhnaya, Elena V. [1 ]
机构
[1] Kyiv Natl Univ Construct & Architecture, Dept Chem, UA-03680 Kiev, Ukraine
[2] Karakalpakian Univ, Dept Chem, Nukus 742012, Uzbekistan
[3] Kiev Natl Taras Shevchenko Univ, Dept Chem, UA-01601 Kiev, Ukraine
[4] Univ Wroclaw, Fac Chem, PL-50383 Wroclaw, Poland
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2009年 / 65卷
关键词
REGIOSELECTIVE SYNTHESIS; METAL-IONS; ACIDS; CRYSTALLIZATION; COMPLEXES;
D O I
10.1107/S1600536809030840
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title structure, C9H11N3O2, is a racemate. The chiral centre is situated at the N-C-N C atom of the imidazolidine ring. The interplanar angle between the mean planes of the pyridine and imidazolidine rings is 89.41 (5)degrees. The methyl group is in a trans position with respect to the pyridine N atom. In the crystal, the molecules are arranged in zigzag layers parallel to the b axis. The molecules within the layers are interconnected by strong O-H center dot center dot center dot N and weak N-H center dot center dot center dot O hydrogen bonds; the former take place between OH groups and amine N atoms and the latter between the amine N atom and the carbonyl O atom. In addition, C-H center dot center dot center dot O interactions are also present.
引用
收藏
页码:O2123 / U1764
页数:10
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